for i in sorted(dict1):
     print(i,dict1[i])

>>>
аслово2 [11, 22, 33, 44, 55]
бслово3 [111, 222, 333, 444, 555]
вслово1 [1, 2, 3, 4, 5]
>>>
 

  
>>> import collections
>>> 
>>> dict1 = {'вслово1': [1, 2, 3, 4, 5],
...          'аслово2': [11, 22, 33, 44, 55],
...          'бслово3': [111, 222, 333, 444, 555]}
>>> 
>>> odict1 = collections.OrderedDict(sorted(dict1.items()))
>>> odict1
OrderedDict([('аслово2', [11, 22, 33, 44, 55]), ('бслово3', [111, 222, 333, 444, 555]), ('вслово1', [1, 2, 3, 4, 5])])
>>>

 dict1 = {
'вслово1' : {
            '2010' : [1, 2],
            '2000' : [3, 4]
            },
'аслово2' : {
            '2010' : [11, 22],
            '2000' : [33, None]}
        } 

 while  True:
    inquiry = input('введите запрос ')
    if inquiry == 'exit': break
    for i in dict1:
         print(i, dict1[i][inquiry][0], dict1[i][inquiry][1]) 

 while True:
    inquiry = input('введите запрос ')
    if inquiry == 'exit': break
    for i in dict.keys(dict1):
        for j, el in dict.items(dict1[i]):
            if j == inquiry: 
                print('%-16s' % i, end='')
                for i in el: print ('%-5s' % i, end='')
                print()

  dict1[i][inquiry][0] 

  dict1 = {
2000 :
[
 ['аслово2' ,[33, None]],
 ['вслово1' ,[3, 4]]
],
2010:
[
 ['аслово2' ,[1, 2]],
 ['вслово1' ,[11, 22]]
]
}

 for word,lst in  dict1[key]:
     print(word,lst)

  babynames = {
    'София, Софья': {
        2012: [3841, 6.0]', 
        2010: [3668, 6.2]',
        2005: [2127, 4.8]',
        2000: [826, 2.4]',
        1990: [193, 0.4]',
    },
    'Виктория': {
        2012: [2219, None],
        2010: [1994, None],
        2005: [1829, None],
        2000: [1076, None],
        1990: [1033, None],
    },
    ...
}

  
София, Софья    3841   6,0%
Мария, Марья    3735   5,8%
...
Виктория        2219
Полина          2051
...